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Effect of Side Chain Rigidity on the Elasticity of Comb Copolymer Cylindrical Brushes: A Monte Carlo Simulation Study

✍ Scribed by Saariaho, Mika; Subbotin, Andrei; Szleifer, Igal; Ikkala, Olli; ten Brinke, Gerrit

Book ID
126295235
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
77 KB
Volume
32
Category
Article
ISSN
0024-9297

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Characteristic conformation of a comb copolymer cylindrical brush consisting of a flexible backbone of 300 beads (black) and 150 semiflexible side chains (white) of length M = 60. Intrinsic stiffness of the side chains is given by k side (s = 165 8)/ M L 0.48. Magnification shows the strongly fluctu

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## Abstract **Summary:** The effects of copolymer sequence distribution on the dynamics of a copolymer in a homopolymer matrix are studied using computer simulations within the framework of the bond‐fluctuation model on blends containing low concentrations (10%) of copolymers dispersed in a homopol