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Effect of S Replacement on the Mechanism of Unimolecular Reactions for Ground-state Thioacetic Acid: A Theoretical Study

✍ Scribed by Aimei LU; Ming KE; Wanjian DING; Ruozhuang LIU

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
323 KB
Volume
27
Category
Article
ISSN
0256-7660

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## Abstract The cluster [W~3~S~4~H~3~(dmpe)~3~]^+^ (1) (dmpe=1,2‐bis(dimethylphosphino)ethane) reacts with HX (X=Cl, Br) to form the corresponding [W~3~S~4~X~3~(dmpe)~3~]^+^ (2) complexes, but no reaction is observed when 1 is treated with an excess of halide salts. Kinetic studies indicate that th