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Effect of rotation on vibrational excitation of H2 by Li+ impact

โœ Scribed by Joachim Schaefer; William A. Lester Jr.

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
438 KB
Volume
20
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Coupled channel calculations of integral cross sections for rotational and vibrational escitation of Hz(X' "3 by collsion with Li+ are reported for 1.2 eV in the cm. system employing an ab initio potential energy surface and numerical vibration-rotation functions of the Kotos-Wolniewicz potehtial function including adiabatic correction.

Pure rotational excitation is found to strongly dominate the inelastic scattering occurring at this energy. Preparation of Hz in various allowed non-zero rotational states is seen to enhance the 0 + 1 vibrational cross section by approsirnately an order of magnitude.

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