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Effect of ring size on the thermal rearrangements of bicyclo[n.1.0]alka-1,n-dienes

✍ Scribed by Billups, W. E.; Baker, B. A.; Chow, W. Y.; Leavell, K. H.; Lewis, E. S.


Book ID
126906232
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
407 KB
Volume
40
Category
Article
ISSN
0022-3263

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trans- andcis-Bicyclo[n.1.0]alk-2-ynes o
✍ Detert, Heiner ;Meier, Herbert πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 808 KB

## Abstract Starting from cycloalkenes, the __cis__‐ or __trans__‐cyclopropano anellated cycloalkynes 2–7 of medium ring size were synthesized. The triple bonds were introduced in the final reaction step either by the fragmentation of the corresponding 1,2,3‐selenadiazoles or by direct dehydration