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Effect of ring size on the rate of reaction of cycloalkyl phenyl ketones with sodium borohydride

✍ Scribed by Sun, Siao-Fang; Neidig, P. R.


Book ID
126988302
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
397 KB
Volume
34
Category
Article
ISSN
0022-3263

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## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from force‐field calculations; __i.e.__ the strain difference between alcohol and ketone (Ξ” strain) and the steric hindrance towards approach of the hydride R. Models