𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of reagent rotation on the reaction D+H2(ν=1)→DH+H

✍ Scribed by N. Sathyamurthy; J.P. Toennies


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
521 KB
Volume
143
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Effect of reagent rotation on bimolecula
✍ Catherine A. Boonenberg; Howard R. Mayne 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 347 KB

Classical trajectory c~cu~ations on fi + H&3 reactions have been carried out. At few collision ener$es the reaction cross section decreases for smnU j. reaching 3 minimum at j = 4, then increases as j increases. It isdso shown rbat rhe isotopic branching ratio is fairly sensitive xo reagent rotation

Effect of reagent rotation on the dynami
✍ Miguel González; Miquel Gilibert; Antonio Aguilar; R. Sayós 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 836 KB

The moderately exotherrnic ion-molecule reaction O+ t Hz and its isotopic variants have been the subject of several dynamical studies in our group. In this work we report an extensive quasiclassical trajectory study on the dynamics of this system at different initial relative energies considering a

The lack of leaving-atom isotope effects
✍ W.H. Breckenridge; Jiang-Hua Wang 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 587 KB

Simple "half-collision" classical trajectories on model potential surfaces show that the lack of leaving-atom isotope effects on initial rotational state distributions P(N) in reactions of the type M\*+H2 (HD) -+MH( v, N) +H (D) would result from decomposition of H-M-H( D) intermediates on anisotrop

Vibrational enhancement of the reaction
✍ I. Schechter; R. Kosloff; R.D. Levine 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 496 KB

The cone or acceptance for H+H= reactive collisions is shown Lo open up upon strelching of the H, bond. AL a given wtmslational energy, the sreric faclor is thus much larger for vibrzkonally cxcircd rcngems as demonswatcd by class&l IrajccLoq compulorions for H+ D?(U) and D+Hz(o). AI a given lolaI c