Effect of Protonation and Interaction with Anions on a Lead(II) Complex with a Lateral Macrobicycle Containing a Phenol Schiff-Base Spacer
✍ Scribed by David Esteban-Gómez; Carlos Platas-Iglesias; Fernando Avecilla; Andrés de Blas; Teresa Rodríguez-Blas
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 204 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Three ferrocenyl Schiff bases containing a phenol moiety have been formed by 1:1 molar condensation of acetylferrocene with 2‐aminophenol, 2‐amino‐5‐picoline or 2‐amino‐5‐chlorophenol. These ligands form 2:1 complexs with cobalt(II), copper(II), nickel(II), and zinc(II) ions. From the d
## Abstract A pentadentate phenol‐containing ligand (H~3~L) with N~2~O~3~ donor atoms yields Ni^II^~2~ (1), Ni^II^~4~ (2), Cu^II^~2~ (3) and Cu^II^~4~ (4) complexes, which have been structurally characterized by X‐ray diffraction. Complex 1 contains a single‐atom __O__‐bridged urea. The compounds w