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Effect of proton spin diffusion on the 13C-{1H} NOE in hydrated macromolecules

✍ Scribed by Lynn W Jelinski; C.E Sullivan; D.A Torchia


Publisher
Elsevier Science
Year
1980
Weight
417 KB
Volume
41
Category
Article
ISSN
0022-2364

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πŸ“œ SIMILAR VOLUMES


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This research was funded by Hungarian Grant OTK A 1144. Jacquelyn Gervay gratefully acknowledges partial support of this research by the Material Characterization Program-State of Arizona. We also thank Dr. T. Gunda, who made it possible for us to use his MOLCONV program and the PCMODEL package. The

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## Abstract The magnitude of the NMR spin‐spin coupling constant, ^3^__J__(CH), between a vicinal ^13^C–^1^H pair depends, __inter alia__, on the value of the torsion angle Ξ¦~CH~(^13^Cο£ΏCο£ΏCο£ΏH) and is influenced by the presence of an electronegative substituent located on the coupling ^13^C nucleus.