Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene
β Scribed by Kiselev, V. D.; Kornilov, D. A.; Kashaeva, E. A.; Potapova, L. N.; Konovalov, A. I.
- Book ID
- 125395722
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2014
- Tongue
- English
- Weight
- 271 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1070-4280
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The pressure effect on the forward and backward rate constants and equilibrium constants of the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene has been investigated in 1,2-dichloroethane up to 1000 kgcm -2 at 298.15 K. The reaction volume obtained from the pressure effect on equi
The activation and reaction volumes (βV /βV) were showing negative volumes of activation (βV Ο½ 0) whereas the others are slightly retarded (βV ΟΎ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum