Effect of pressure on the free radical solution polymerization of acrylonitrile and methylmethacrylate
β Scribed by Baijayantimala Mohanty; Sunanda K. Palit; Mukul Biswas
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1987
- Tongue
- English
- Weight
- 228 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0887-6258
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π SIMILAR VOLUMES
## Abstract Application of shear is found to increase the rate of solution polymerization of acrylonitrile in N,Nβdimethyl formamide (DMF) initiated by benzoyl peroxide by as much as 400 percent of the value in absence of shear. The solvent DMF acts as an inert and maintains a homogeneous reaction
## Abstract Summary: The influence of the Laplace pressure in polymer emulsion particles during aqueous heterogeneous free radical polymerization on the polymerization kinetics has been investigated. Calculations were carried out based on experimentally reported pressure dependences of propagation