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Effect of pressure on the (2 + 2) cycloaddition of ethoxycyclopropane to tetracyanoethylene

โœ Scribed by Petrus G. Wiering; Herbert Steinberg

Book ID
104588786
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
369 KB
Volume
105
Category
Article
ISSN
0165-0513

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Effect of pressure on the (2 + 2) cycloa
Effect of pressure on the (2 + 2) cycloaddition of cyclopropanone diethyl acetal to tetracyanoethylene
โœ Petrus G. Wiering; Herbert Steinberg ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 271 KB

## Abstract The pressure dependence of the (2 + 2) cycloaddition of cyclopropanone diethyl acetal to tetracyanoethylene in methylene chloride and acetonitrile has been studied. The reaction is about ten times faster in the less polar methylene chloride in the pressure range 1โ€2000 atm. The volume o