Effect of oxyanions on the glucose isomerase catalysed equilibrium: 1. Complexes of d-glucose and d-fructose with germanate
โ Scribed by Heather Pelmore; P.J. Somers
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 473 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0141-0229
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๐ SIMILAR VOLUMES
Both D-glucose and D-fructose bind NaOH at 303 K in aqueous medium, with association constants of 24 and 25 L.mol-', respectively. The polarity of the medium significantly affects the association process. Calculation has shown that, at 303 K, 1 ,Cdioxane, acetone, and ethyl alcohol can totally stop
The interaction of D-glucose with the hydrated alkaline-earth metal halides has been studied in solution, and adducts of the type Mg(D-glucose)X2.4 H2O, Ca(D-glucose)X2.4 H2O, and Ca(D-glucose)2X2.4 H2O, where X = Cl- and Br-, have been isolated, and characterized by means of F.t.-i.r. and 1H-n.m.r.