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Effect of oxide and sulfide bridging ligands on the structure and magnetic properties of tetranuclear cyclopentadienyl chromium clusters

✍ Scribed by I. L. Eremenko; A. A. Pasynskii; G. Sh. Gasanov; Sh. A. Bagirov; O. G. Éllert; V. M. Novotortsev; V. T. Kalinnikov; Yu. T. Struchkov; V. E. Shklover

Book ID
112444474
Publisher
Springer
Year
1983
Tongue
English
Weight
165 KB
Volume
32
Category
Article
ISSN
1573-9171

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~