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Effect of oxidant on the reaction of [RhCl(cyclooctadiene)(phosphine)] with 1-hexene

✍ Scribed by Wojciech Duczmal; Bogdan Marciniec; Elżbieta Śliwińska; Wlodzimierz Urbaniak


Publisher
Springer
Year
1989
Tongue
English
Weight
427 KB
Volume
14
Category
Article
ISSN
0340-4285

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Trisubstituted silanes, HSiR 3 \_,X, (R = Me or Et, X = C1, OEt, or Ph; n =0-3) oxidatively add to the complex [RhCl(cod . Subsequent steps of hydrosilylation follow, i.e. cis-insertion of the alkene (u-a rearrangement) and then reductive elimination of the product, according to the general Chalk a

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The effect of ethylene pressure on the copolymerization of ethylene with 1hexene was studied. The results show an increasing of productivities (g of polymer/ n Zr h) with pressure. This tendency was not observed for the activity (g of polymer/ n Zr h bar) that decreases when pressure is raised. When