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Effect of nucleophile basicity on intramolecular nucleophilic aminolysis reactions of carbonate diesters

โœ Scribed by Fife, Thomas H.; Hutchins, J. E. C.

Book ID
125484784
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
847 KB
Volume
103
Category
Article
ISSN
0002-7863

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## Abstract The kinetics of the reactions of 4โ€methylphenyl, phenyl, and 4โ€chlorophenyl 2,4,6โ€trinitrophenyl carbonates (**1**, **2**, and **3**, respectively) with a series of anilines and secondary alicyclic (SA) amines has been carried out spectrophotometrically in 44 wt% ethanolโ€“water, at 25.0ยฐ