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Effect of non-peripheral alkyloxy substituents on the structure and spectroscopic properties of metal-free phthalocyanines

✍ Scribed by Mei-Jin Lin; Jun-Dong Wang

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
527 KB
Volume
837
Category
Article
ISSN
0022-2860

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✦ Synopsis

Four non-peripheral alkyloxy substituted metal-free phthalocyanines have been synthesized and characterized with X-ray crystal structure, IR, UV-vis and 1 H NMR. It is found that the center caves of Pc skeletons were expanded but their ring currents were reduced by the introduction of alkyloxy substituents on the non-peripheral positions.

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