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Effect of NO2-modification of Tyr83 on the reactivity of spinach plastocyanin with inorganic redox partners [Fe(CN)6]3−/4− and [Co(phen)3]3+/2+

✍ Scribed by Hans E.M. Christensen; Jens Ulstrup; A. Geoffrey Sykes

Book ID
113268025
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
779 KB
Volume
1039
Category
Article
ISSN
0167-4838

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__