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Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs

✍ Scribed by Zlotea, Claudia; Phanon, Delphine; Mazaj, Matjaz; Heurtaux, Daniela; Guillerm, Vincent; Serre, Christian; Horcajada, Patricia; Devic, Thomas; Magnier, Emmanuel; Cuevas, Fermin; Férey, Gérard; Llewellyn, Philip L.; Latroche, Michel

Book ID
120027132
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
267 KB
Volume
40
Category
Article
ISSN
1477-9226

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Effect of NH2 and CF3 functionalization
Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs
✍ Zlotea, Claudia; Phanon, Delphine; Mazaj, Matjaz; Heurtaux, Daniela; Guillerm, V 📂 Article 📅 2011 🏛 Royal Society of Chemistry 🌐 English ⚖ 267 KB

The hydrogen adsorption capacity and heat of adsorption at 77 K have been evaluated for several porous metal terephthalate MOFs (MIL-53(Fe), MIL-125(Ti) and UiO-66(Zr)), as well as in their -NH 2 and -(CF 3 ) 2 functionalized isoreticular structures. The capacity of hydrogen is basically related to