Effect of negative pressure on melting behavior of spherulites in thin films of several crystalline polymers

✍ Scribed by Andrzej Pawlak; Ewa Piorkowska

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 244 KB
• Volume: 74
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19991107)74:6<1380::aid-app9>3.0.co;2-m

✦ Synopsis

The melting behavior of spherulites in thin films of isotactic polypropylene, poly(ethylene oxide), poly(methylene oxide), and poly(ethylene adipate) crystallized isothermally at various temperatures has been studied by polarized light microscopy. The local increase of melting temperature in regions surrounding cavities and multiple boundary points, dependent on the crystallization temperature, was observed in all studied polymers. In pockets of occluded melt an arising negative pressure lowers an equilibrium melting temperature; hence, decreases an undercooling, which results in the increase of lamellae thickness and their melting temperature. The elevation of melting temperature and the negative pressure buildup depend on the polymer and the crystallization temperature.