Effect of nanoclay on the thermal, mechanical, and crystallization behavior of nanofiber webs of nylon-6

✍ Scribed by Khalid Saeed; Soo Young Park

• Publisher: Society for Plastic Engineers
• Year: 2011
• Tongue: English
• Weight: 446 KB
• Volume: 33
• Category: Article
• ISSN: 0272-8397
• DOI: 10.1002/pc.21262

✦ Synopsis

Abstract

Nylon‐6 and nanoclay/nylon‐6 composite nanofibers were prepared by electrospinning technique, in which formic acid was used as a solvent for good solubility of nylon‐6. The diameter of nylon‐6 and nanoclay/nylon‐6 nanofibers was below 350 nm and had smooth surfaces. The DSC heating curves of nylon‐6 and composites nanofibers show two endotherm behaviors, T~m~~1~ (about 214°C) and T~m~~2~ (about 220°C), corresponding to the melting events of γ‐form and α‐form crystals, respectively. The WAXs study showed that the γ‐crystalline phase predominantly present in both nylon‐6 and nanoclay/nylon‐6 nanofibers. The mechanical properties of the nanoclay/nylon‐6 composite nanofibers were higher than neat nylon‐6 electrospun nanofibers, which was decreased as the quantity of the clay increased. It might be due to the aggregation of nanoclay at high concentration. The thermal properties of the composite nanofibers were higher than neat nylon‐6 nanofibers. POLYM. COMPOS., 2012. © 2011 Society of Plastics Engineers