The effects of diphenyltin dichloride (DPhT), triphenyltin chloride (TPhT) and tetraphenyltin (TTPhT) on the thermotropic phase behaviour of phosphatidylcholine bilayers were studied. All the phenyltin compounds investigated affected phase transitions differently. TTPhT broadened the main phase tran
EFFECT OF MODEL STRUCTURE ON THE ACCURACY AND UNCERTAINTY OF RESULTS FROM WATER QUALITY MODELS
✍ Scribed by M. VAN DER PERK
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 252 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0885-6087
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✦ Synopsis
Eight one-dimensional steady-state models with dierent complexity, which describe the phosphate concentration as a function of the distance along a river, were examined with respect to accuracy and uncertainty of the model results and identi®ability of the model parameters by means of combined calibration and sensitivity analysis using Monte Carlo simulations. In addition, the models were evaluated by the Akaike information criterion (AIC). All eight models were calibrated on the same data set from the Biebrza River, Poland. Although the accuracy increases with model complexity, the percentage of explained variance is not signi®cantly improved in comparison with the model that describes the phosphate concentration by means of three parameters. This model also yields the minimum value of the AIC and the parameters could be well identi®ed. Identi®cation of the model parameters becomes poorer with increasing model complexity; in other words the parameters become increasingly correlated. This scarcely aects the uncertainty of the model results if correlation is taken into account. If correlation is not taken into account, the uncertainty of model results increases with model complexity.
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