Effect of micelle formation on optical rotatory dispersion of β-D-octyl glucoside
✍ Scribed by P. Mukerjee; J. Perrin; E. Witzke
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 345 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-3549
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## Abstract The effect of salts on the coil‐to‐helix transition of poly‐α‐amino acids was investigated by optical rotatory dispersion and potentiometric titration techniques. Both charge‐dependent and charge‐independent contributions to the free energy were considered. The free energy of formation
Molecular dynamics simulations of methyl-P-D-glucoside in water are performed. Although the tg conformation of the hydroxymethylgroup is found to be the lowest in energy for the isolated molecule, it appears to be unstable in water. The well-known absence of a significant amount of the tg conformati