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Effect of metal ions in organic synthesis : Part XXXIII. 2-hydroxy-4-pyrrolines as stable intermediates in the synthesis of 1-aminopyrrole derivatives

✍ Scribed by Orazio A. Attanasi; Mario Grossi; Franco Serra-Zanetti; Elisabetta Foresti


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
453 KB
Volume
43
Category
Article
ISSN
0040-4020

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Treatment of 1,4-diketones with liquid ammonia gives high yields of isolable 2-hydroxy-3,4-dihydro-ZH-pyrrole intermediates. These intermediates, which do not appear to have been observed previously in the ?aal-norr s have been fully characterized by i-r. r and Hand nthesis with anaaonia, C n.m.r. s