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Effect of medium on the rate constant of decarbonylation of phenylacetyl radical

✍ Scribed by Yu. P. Tsentalovich; O. A. Kurnysheva; N. P. Gritsan

Book ID
110274842
Publisher
Springer
Year
2001
Tongue
English
Weight
302 KB
Volume
50
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

On the rates of decarbonylation of hydro
On the rates of decarbonylation of hydroxyacetyl and other acyl radicals
✍ J. -K. Vollenweider; H. Paul πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 452 KB

The rate of decarbonylation of the hydroxyacetyl radical in acetonitrile is measured by effect modulated ESR spectroscopy and found to be log ( k D / s ') = (11.0 2 1.5)-(2.3RT) -' (37 t 8)kJ/mol. The result is shown to be reasonably well connected with a variety of decarbonylation data known for ot

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✍ Xiangyang Zhang; Werner M. Nau πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 79 KB πŸ‘ 2 views

Five aryl-substituted phenacetyl radicals (X = p-MeO, p-Me, H, p-Cl, p-CF 3 ) were generated by laser photolysis of the corresponding dibenzyl ketones in n-hexane and acetonitrile. The decarbonylation reaction was monitored through the rise in time-resolved absorption of the benzyl radical chromopho