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Effect of media on interaction of isocyanates with alcohols


Book ID
114046552
Publisher
Elsevier Science
Year
1966
Tongue
English
Weight
85 KB
Volume
5
Category
Article
ISSN
0021-9517

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DMF and DMSO catalyse the reaction of butanol with PhNCO but inhibit that with aliphatic isocyanates, due to formation of an active 1 : 1 charge transfer complex with the aromatic isocyanate. Similarity was found in the mode of catalysis of the urethane reaction with these solvents to that with tert