Conformational analysis of cationic (R,S
โ
Takashi Hashihayata; T. Punniyamurthy; Ryo Irie; Tsutomu Katsuki; Munetaka Akita
๐
Article
๐
1999
๐
Elsevier Science
๐
French
โ 920 KB
The structures of (R,S)-and (RR)-(saJen)manganese(III) complexes [(R,S)-2a,b and (R,R)-2a,b] possessing axial chirality as one of their two chiral elements were unambiguously determined by X-ray crystallographic analysis. The basal salen ligands of the complexes were demonstrated to adopt a stepped