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Effect of light on the electrooxidation of adsorbed allyl alcohol on platinum electrodes

✍ Scribed by Reinaldo S. Gonçalves; JoséA. Mallmann; Erich W. Grabner

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
523 KB
Volume
40
Category
Article
ISSN
0013-4686

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✦ Synopsis

The electrooxidation of adsorbed species formed during ally1 alcohol adsorption on a platinum electrode has been studied. Significant differences between measurements in the dark and under illumination confirm that the adsorption process is affected by the incidence of polychromatic light on the electrode surface. This may be attributed to a light-induced activation effect of the water adsorption on the electrode surface.

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Electrooxidation of benzyl alcohol on Pt
Electrooxidation of benzyl alcohol on Pt-Nafion composite electrode
✍ Mikito Yasuzawa; Kyouhiro Kan; Akira Kunugi; Zempachi Ogumi; Zen-Ichiro Takehara 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 271 KB

The electrooxidation of benzyl alcohol was investigated employing a Pt-Nation composite electrode in both polar and non-polar solvents. The use of hexane as a solvent caused the current effciency for benzaldehyde formation to increase greatly compared with that in acetonitrile. Furthermore, the stab