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Effect of Ligand Substituent Coordination on the Geometry and the Electronic Structure of Cu(II)-Diradical Complexes

✍ Scribed by Rakshit, Richa; Ghorai, Samir; Biswas, Soumava; Mukherjee, Chandan


Book ID
121855583
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
881 KB
Volume
53
Category
Article
ISSN
0020-1669

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Effect of coordination structure on the
✍ Yuzo Nishida; Masataka Takeuchi; Naoyasu Oishi; Sigeo Kida πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 460 KB

## Catalytic activities of mononuclear copper(H) complexes were studied for the reactions, 1) O1 oxidation of N,N,N',N'-tetramethyl-1,4-diaminobenzene, and 2) decomposition of hydrogen peroxide. For both reactions, distorted tetrahedral complexes showed much higher reactivities than the complexes