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Effect of Ligand Modification on Rhodium-Catalyzed Homogeneous Hydroformylation in Supercritical Carbon Dioxide

✍ Scribed by Palo, Daniel R.; Erkey, Can


Book ID
125893539
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
159 KB
Volume
19
Category
Article
ISSN
0276-7333

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## Abstract Rhodium‐catalyzed hydroformylation of 1,5‐hexadiene to dialdehydes was investigated in compressed CO~2~ and in toluene using different fluorinated phosphane compounds as ligands at a temperature of 60 Β°C. Product yields depend greatly on the ligand used and, of the ligands examined, tri