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Effect of ligand geometry on cobalt-59 NMR relaxation in hexakis(phosphite)cobalt(III) complexes

✍ Scribed by Socol, Steven M.; Lacelle, Serge; Verkade, John G.

Book ID
127322283
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
524 KB
Volume
26
Category
Article
ISSN
0020-1669

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A broad study of the 59C0 N M R of cobalt(1II) porphyrin complexes with axial amine ligands in a variety of solvents is reported. The data are presented in tabular form, as are the numerical correlations of chemical shift, 6, a d line width, ol/\*, using the Kamlet-Taft equation. The dependence of 6