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Effect of lanthanide contraction and rigid ligand on the structure of salen-type lanthanide complexes

✍ Scribed by Chen, Peng; Chen, Han; Yan, Pengfei; Wang, Yan; Li, Guangming


Book ID
120292285
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
278 KB
Volume
13
Category
Article
ISSN
1466-8033

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## Abstract Four new disulfoxide‐Ln^III^ complexes, [Ln(L)~2~(NO~3~)~3~]__~n~__ {Ln = La (1), __n__ = __n__; Ln = Gd (2), Dy (3) and Yb (4), __n__ = 2}, have been prepared by the reaction of Ln(NO~3~)~3~Β·__n__H~2~O with __meso__‐1,3‐bis(ethylsulfinyl)propane (__meso__‐L) in methanol/triethylorthofo