Abshact-In order to throw light on ion-solvent interactions, the salvation numbers of electrolytes in different mixed solvents (methanol + water and ethanol + water mixtures) have been determined using ultrasonic interferometer. The anomalies in the salvation number of cations (in aqueous solutions)
Effect of ion solvation on the diffuse layer structure in mixed electrolytes
โ Scribed by A. A. Chernenko
- Book ID
- 110200523
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 260 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1023-1935
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๐ SIMILAR VOLUMES
Several anions which are reduced at potentials more anodic than the point of zero charge (p.z.c.) show a characteristic minimum in the polarographic current at potentials just more negative than this point, provided that the supporting electrolyte is absent or else present at a low concentration 1 .
The thickness 6 of the Nemst diffusion layer depends on the nature of the gas evolved, on the mode of formation of bubbles, on cd j and on the height of the electrode. Platinum electrodes of various heights were used at which hydrogen, oxygen or chlorine was evolved. 6 decreases in the sequence hyd