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Effect of internal and translational energy on the NH3+(ν) + D2 ion-molecule reaction

✍ Scribed by Richard J.S. Morrison; William E. Conaway; Richard N. Zare

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
514 KB
Volume
113
Category
Article
ISSN
0009-2614

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✦ Synopsis

Using 2 + 1 multipho ton ionization, NH; is prepared in sclcctcd levels of the "2 bending mode (v = O-7) and the NH:(u) + Da reaction is studied as a function of the center-of-mass collision energy (l-10 eV). The exchange channel (NH2D*+ HD or H + D) is enhanced by ion vibrational ehcitation wherex the addition channel (NH3 D+ + D) is'alrnost unaffected.

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