✦ LIBER ✦

Effect of intermediate state depolarization on photoelectron angular distributions from molecules following (1+1′) REMPI

✍ Scribed by Katharine L. Reid

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 531 KB
Volume: 215
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)89257-i

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✦ Synopsis

We discuss the use of ( 1 + 1') resonance-enhanced multiphoton ionization (REMPI) with a time delay between the excitation and ionization processes as a method of probing intramolecular dynamics. In particular, we discuss the effect of these dynamics on photoelectron angular distributions (PADS). As a simple example, we present expressions for PADS following REMPI via an intermediate state that undergoes hypertine depolarization, and apply this to the A *Z+ state of nitric oxide.