Effect of Interfacial Failure on the Viscosity of High-density Polyethylene

✍ Scribed by Chi-Ming Chan; Shui Han Zhu

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 271 KB
• Volume: 8
• Category: Article
• ISSN: 1042-7147
• DOI: 10.1002/(sici)1099-1581(199704)8:4<257::aid-pat635>3.0.co;2-s

✦ Synopsis

The effect of a processing agent (Dynamar) on the viscosity and surface properties of high-density polyethylene (HDPE) has been studied. A capillary rheometer was used to measure the viscosity of HDPE compounds containing various concentrations of Dynamar as a function of time at constant apparent shear rates. The shear rates used are 250 and 500 sec Ϫ 1 . The addition of a small amount of Dynamar leads to a marked reduction in viscosity. The viscosity decreases dramatically initially, then levels off to an equilibrium. The rate of the viscosity reduction and the equilibrium viscosity value depend upon the Dynamar concentration and the shear rate. This phenomenon can be explained by the migration of Dynamar from the bulk to the interface of HDPE melt and die wall, resulting in the formation of a lubrication layer. X-ray photoelectron spectroscopy and scanning secondary ion mass spectrometry analyses of the extrudates from a slit die reveal a low concentration of Dynamar at the surface. Adhesive failure at the Dynamar and HPDE interface is attributed to a reduction in viscosity.