## Abstract Ligands, such as Me~4~cyclam and anionically charged BPAA, providing low values of __k__~da~ and less efficient for ATRP with alkyl halides, were successfully used for ATRP in the presence of alkyl pseudohalides as initiators/chain transfer agents, resulting in wellβcontrolled PSt and P
Effect of Initiator and Ligand Structures on ATRP of Styrene and Methyl Methacrylate Initiated by Alkyl Dithiocarbamate
β Scribed by Kwak, Yungwan; Matyjaszewski, Krzysztof
- Book ID
- 119962613
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 180 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Initiators for continuous activator regeneration in atom transfer radical polymerization (ICAR ATRP) is a new technique for conducting ATRP. ICAR ATRP has many strong advantages over normal ATRP, such as forming the reductive transition metal species in situ using oxidatively stable tra
The free radical dispersion polymerization of styrene (St) and methyl methacrylate (MMA) initiated by poly(oxyethylene) (PEO) macroazoinimer (MIM-400) in water/ethanol, was investigated at three different temperatures (50, 60 and 80 8C) for seven polymerization times (3, 6, 9, 12, 24, 36 and 48 h).