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Effect of hydroxyl group substituents on pyran ring on hydrolysis rate of benzoates: 2-Tetrahydropyranyl benzoate

โœ Scribed by Anwar Hussain; James Truelove


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
184 KB
Volume
68
Category
Article
ISSN
0022-3549

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Substituent and Isotope Effects on the H
โœ Mai-Huong Bui-Nguyen; Hans Dahn; John F. McGarrity ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 625 KB

The overall kinetic solvent isotope effects on the acid catalyzed hydrolysis of a series of 2-aryl-2-diazocarboxylic esters ArCN2COOCH3, and one 2-aryl-2-diazocarboxamide C6H5CH2CON (CH,), vary inversely with the reactivity of the substrate, between limits of 3.14 and 1.46. A linear Hammett plot for