Ethylene polymerization was carried out with a novel in-situ-supported metallocene catalyst that eliminates the need for a supporting step before polymerization. The influence of the metallocene amount, aluminum to zirconium mole ratio, temperature, pressure, and cocatalyst type on polymerization ki
β¦ LIBER β¦
Effect of hydrogen on ethylene polymerization using in-situ supported metallocene catalysts
β Scribed by Kyung-Jun Chu; Joao B. P. Soares; Alexander Penlidis
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 94 KB
- Volume
- 201
- Category
- Article
- ISSN
- 1022-1352
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## Abstract A kinetic study of ethylene homopolymerization is conducted with a supported unbridged metallocene catalyst in a slurry reactor. The effects of operational parameters such as the reaction temperature and pressure on kinetics are investigated. The kinetic parameters which have been deter