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Effect of high pressure on the steric specificity of the helferich glycosylation

✍ Scribed by N. K. Kochetkov; V. M. Zhulin; E. M. Klimov; N. N. Malysheva; Z. G. Makarova


Book ID
112561934
Publisher
Springer
Year
1987
Tongue
English
Weight
136 KB
Volume
36
Category
Article
ISSN
1573-9171

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Effect of high pressure on sterically co
✍ GΓ©rard Jenner πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 79 KB

The effect of high pressure is examined in 3-CC (Passerini) reactions. This effect is small when moderately hindered reactants are involved. However, particularly in the case of bulky isocyanides, the sensitivity of the reaction to pressure increases with increasing steric congestion in line with ea