Effect of High Pressure on the Kinetics and Mechanism of Thermolysis of Organic Peroxides in Solution
β Scribed by V. L. Antonovskii; V. M. Zhulin
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 51 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent
Recent reports by Nakano and Minoura',\* have claimed that the mechanical degradation of high polymers in solution at low concentrations is enhanced if the polymer is dissolved in a thermodynamically "good" solvent. The minimum concentration used in their study (c = 0.04%) gave solutions