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Effect of high pressure on “cage” reactions of radicals during decomposition of azobisisobutyronitrile

✍ Scribed by M. Ya. Botnikov; V. M. Zhulin; L. G. Bubnova; G. A. Stashina


Book ID
112437374
Publisher
Springer
Year
1977
Tongue
English
Weight
255 KB
Volume
26
Category
Article
ISSN
1573-9171

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Radical reactions initiated by chelate c
✍ Horanská, V. ;Bartoň, J. ;Maňásek, Z. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 496 KB

## Abstract The decomposition of αα′‐azobisisobutyronitrile (AIBN) in the presence of bis(‐)‐ephedrine copper (II) chelate was studied in 1,3,5‐trimethylbenzene. It was found that the chelate accelerated the decomposition of AIBN and at the same time interacted with the free radicals arising in the