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Effect of halogen substituents on nmr chemical shifts. 13C spectra of bicyclic halides.

✍ Scribed by Kenneth B. Wiberg; William E. Pratt; William F. Bailey

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 226 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85755-5

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✦ Synopsis

The question of the relative importance of through-bond and through-space interactions in determining 13C nmr chemical shifts, as well as the relative importance of electric field effects and induced magnetic fields are still not answered. We have examined the 13C nmr spectra of a number of sets (F,Cl,Br,I) of bicyclic halides as well as other aliphatic and alicyclic halides. Some

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