Effect of glycerol cross-linking and hard segment content on the shape memory property of polyurethane block copolymer
โ Scribed by Byoung Chul Chun; Mi Hwa Chong; Yong-Chan Chung
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 463 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-2461
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๐ SIMILAR VOLUMES
## Abstract Poly(ฮตโcaprolactone)โbased segmented polyurethanes (PCLUs) were prepared from poly(ฮตโcaprolactone) diol, diisocyanates (DI), and 1,4โbutanediol. The DIs used were 4,4โฒโdiphenylmethane diisocyanate (MDI), 2,4โtoluenediisocyanate (TDI), isophorone diisocyanate (IPDI), and hexamethylene di
Shape-memory polyurethanes (PUs) were synthesized by 4,4 -diphenylmethane diisocyanate (MDI), 1,4-butanediol (BD), and poly(tetramethyl oxide)glycol (PTMO). The morphology of PUs was studied using DSC, DMA, and TEM. The results indicated that the PUs would show different morphology by changing the m