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Effect of fluoroalkyl substituents on the reaction of alkylchlorosilanes with silica surfaces

โœ Scribed by Tripp, C. P.; Veregin, R. P. N.; Hair, M. L.


Book ID
127202186
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
636 KB
Volume
9
Category
Article
ISSN
0743-7463

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The gas-phase reaction of (3-aminopropyl)dimethylethoxysilane (APDMES) with silica with and without amine catalysts has been studied using infrared spectroscopy. Evidence is provided that shows that the aminosilane initially adsorbs via hydrogen bonding of both ethoxy and aminopropyl moieties of the