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Effect of excess reactant on the steric course of carbonyl olefination

✍ Scribed by L.D. Bergelson; V.A. Vaver; L.I. Barsukov; M.M. Shemyakin


Book ID
104213277
Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
289 KB
Volume
5
Category
Article
ISSN
0040-4039

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The steric course of the palladium promo
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A wide variety of nucleophiles have been observed to add to olefins complexed to palladium. 2 When the nucleophile, e.g. acetate, is added externally trana-addition appears to take place. 2,3.4,5 With aryl-and alkylpalladium compounds, where the aryl and alkyl groups are essentially covalently bou