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Effect of ethylene glycol on the formation of extended crystals of M1/3Co2/3C2O4· 2H2O (M = Zn, Mn) oxalates and their thermolysis products

✍ Scribed by O. I. Gyrdasova; V. N. Krasil’nikov; I. G. Grigorov; G. V. Bazuev


Book ID
110180348
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
247 KB
Volume
51
Category
Article
ISSN
0036-0236

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## Abstract Crystals of Zn(NO~3~)~2~· H~2~O and Mn(NO~3~)~2~· 2 H~2~O were synthesized by heating melts of the respective penta- or hexahydrates. Single crystal X-ray diffraction of the two highly hygroscopic phases reveals new sheet-structure types: Zn(NO~3~)~2~· H~2~O [__Pbca__,__a__= 9.722(1),__