Effect of Electrostatic Interactions and Dynamic Disorder on the Distance Dependence of Charge Transfer in Donor−Bridge−Acceptor Systems†
✍ Scribed by Grozema, Ferdinand C.; Berlin, Yuri A.; Siebbeles, Laurens D. A.; Ratner, Mark A.
- Book ID
- 115313415
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 402 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0022-3654
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## Abstract We estimate, at a full quantum‐chemical level, the various molecular parameters governing the rate of photoinduced charge generation and charge recombination in model organic structures containing a donor and an acceptor unit in view of the possible use of such systems in organic solar
Photoinduced electron-transfer rates are reported for two pairs of rigid bichromophoric molecules 1(6)/2(6) and 1(8)/2( 8). In the first pair electron donor and acceptor are separated by six, in the second pair by eight, carbon-carbon o bonds. While these o bonds provide an all-trans coupling path