Effect of electronic excitation on ultrafast rotational motion of dye molecules
β Scribed by D. Reiser; A. Laubereau
- Book ID
- 107733006
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 370 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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Electronically excited CH was produced by multiphoton dissociation of acetone at 248 nm. Measurements of the electronic relaxation of specific rotational levels of CH( A 'A) by acetone show that the quenching efficiency decreases as N' is increased, in accordance with room temperature results on OH\
## Abstract In the theoretical descriptions of natural and magnetoβoptical activity it is customary to average classically over molecular orientations. We develop a theoretical description of the two phenomena that includes the correct quantum mechanical representation of the rotational motion in o