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Effect of electrolyte on the mean interfacial solvent and electrostatic characteristics of cationic micelles

โœ Scribed by Calum J. Drummond; Franz Grieser; Thomas W. Healy

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
572 KB
Volume
140
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The solvatochromic acid-base indicator 2,6diphenyl-4-(2,4,6-triphenyl-l-pyridinio)phenoxide, ET( 30), has been employed to ascertain the effect of electrolyte on the effective interfacial dielectric constant and the mean electrostatic surface potential, vuo, of dodecyltrimethylammonium bromide and dodecyltrimethylammonium chloride micelles. The micellar w0 values have been interpreted by comparing them with the w0 values calculated from the unmodified non-linearized Poisson-Boltzmann equation.

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