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Effect of Electrode Density of States on the Heterogeneous Electron-Transfer Dynamics of Osmium-Containing Monolayers

✍ Scribed by Forster, Robert J.; Loughman, Paul; Keyes, Tia E.

Book ID
126437392
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
99 KB
Volume
122
Category
Article
ISSN
0002-7863

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Effect of ionβ€”electrode contact on the e
Effect of ionβ€”electrode contact on the energetics of the heterogeneous electron transfer
✍ Xinfu Xia; Max L. Berkowitz πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 555 KB

Using molecular dynamics computer simulation technique we studied the effect of the ion-electrode contact on the energetics of electron transfer reactions. We observed that when the solvation shell of the ion undergoes large changes due to the ion transfer from the bulk to the interface, the energet